| Name | Party | Tenure |
| Dayanand Bandodkar | Maharashtrawadi Gomantak Party | 1963-1967 |
| Shashikala Kakodkar | Maharashtrawadi Gomantak Party | 1967-1973 |
| Pratapsingh Rane | Indian National Congress | 1973-1979 |
| president rule | – | 29 Apr 1979 |
| Shankar Laad | Progressive Democratic Front | 1979-1980 |
| Pratapsingh Rane | Indian National Congress | 1980-1985 |
| Dr. Wilfred de Souza | Progressive Democratic Front | 1985-1986 |
| Pratapsingh Rane | Indian National Congress | 1986-1990 |
| Ravi Naik | Indian National Congress | 1990-1991 |
| Churchill Alemao | United Goans Democratic Party | 1991-1993 |
| Wilfred de Souza | Goan People’s Party | 1993-1994 |
| Luizinho Faleiro | Indian National Congress | 1994-1998 |
| Francisco Sardinha | Indian National Congress | 1998-1999 |
| Luizinho Faleiro | Indian National Congress | 1999-2000 |
| Manohar Parrikar | Bharatiya Janata Party | 2000-2002 |
| president rule | – | jun 2002-feb 2003 |
| Manohar Parrikar | Bharatiya Janata Party | 2003-2005 |
| Pratapsingh Rane | Indian National Congress | 2005-2007 |
| Digambar Kamat | Indian National Congress | 2007-2012 |
| Manohar Parrikar | Bharatiya Janata Party | 2012-2014 |
| Laxmikant Parsekar | Bharatiya Janata Party | 2014-2017 |
| Manohar Parrikar | Bharatiya Janata Party | 2017-2019 |
| Pramod Sawant | Bharatiya Janata Party | 2019-2023 |
| Vishwajit Rane | Bharatiya Janata Party | 2023-Present |
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